Density, Viscosity and Surface Tension of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Tricyanomethanide with Benzothiophene

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Density, Viscosity and Surface Tension of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Tricyanomethanide with Benzothiophene

The effects of temperature and composition on the density and viscosity of pure benzothiophene and ionic liquid (IL), and those of the binary mixtures containing the IL 1-butyl-1-methylpyrrolidynium tricyanomethanide ([BMPYR][TCM] + benzothiophene), are reported at six temperatures (308.15, 318.15, 328.15, 338.15, 348.15 and 358.15) K and ambient pressure. The temperature dependences of the den...

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Phase Behaviour and FTIR Spectra of Ionic Liquids: The Mixtures of 1-Butyl-1-methylpyrrolidinium Chloride and TaCl5

A series of ionic liquids consisting of 1-butyl-1-methylpyrrolidinium chloride (Pyr14Cl) and TaCl5 at molar ratios of Pyr14Cl in the range of 0.85 – 0.20 was synthesized. They exhibit potential application as electrolytes for the electrochemical deposition of tantalum. The thermal behaviour of the Pyr14Cl-TaCl5 mixtures was investigated, using differential scanning calorimetry (DSC) to estimate...

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Measurement of Volumetric and Viscometric Properties of Binary Mixtures of Methyl Tert-butyl Ether (MTBE) + 1-Alcohol from 293.15 to 308.15 K and at Atmospheric Pressure

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Spectroscopy and Electrochemistry of Tantalum(V) in 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate

FTIR spectroscopic and electrochemical characterizations of tantalum(V) in 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate (Pyr14TFMS)-TaCl5 ionic liquids are performed with 5, 15, and 35 mol% TaCl5 as the media for potential electrochemical application. On the basis of FTIR spectra the electrochemical active species are identified as follows: [TaOCl4]−, [TaOCl5]2−, [TaCl5F]−, and [TaCl...

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Measurement of Selected Thermophysical and Viscosity of Binary Mixtures of Nitromethane with 2-Propanol, 2-Butanol and 2-Pentanol

The density and viscosity values at T= (293.15 to 323.15) K for binary mixtures of nitromethane with 2-propanol, 2-butanol and 2-pentanol were measured over the entire composition range. From the experimental data, excess molar volumes, thermal expansion coefficients, excess thermal expansions, partial molar volumes at infinite dilution and deviations in viscosity were calculated. The results w...

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ژورنال

عنوان ژورنال: Journal of Solution Chemistry

سال: 2014

ISSN: 0095-9782,1572-8927

DOI: 10.1007/s10953-014-0257-1